Module Details
Module Code: |
PHAR S8010 |
Full Title:
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Biopharmaceutical Analysis
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Valid From: |
Semester 1 - 2013/14 ( September 2013 ) |
Language of Instruction: | |
Module Owner:: |
annamarie rogers
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Module Description: |
The aims of this module are to provide students with a detailed understanding of a range of specialised investigational techniques and their application areas and associated problems within the biopharmaceutical and related industries.
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Module Learning Outcome |
On successful completion of this module the learner will be able to: |
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Module Learning Outcome Description |
MLO1 |
Assess the principles and applications of, and the instrumentation used for, advanced aspects of modern analytical techniques such as high performance liquid chromatography (HPLC), gas chromatography and mass spectrometry. |
MLO2 |
Perform High Performance Liquid Chromatography, Gas Chromatography and Capillary Eectrophoresis in the laboratory. |
MLO3 |
Demonstrate how chromatographic systems and separations can be numerically evaluated and hence how they can be used to identify sample materials and determine concentrations by reference to the performance of standards. |
MLO4 |
Compare and contrast specialised techniques such as capillary electrophoresis, ELISA, Western Blot analysis, SDS-PAGE and 2D SDS-PAGE. |
MLO5 |
Evaluate and assess the application areas and associated limitations of the above techniques within the spectrum of biopharmaceutical sciences (raw material, intermediate product and end-product). |
Pre-requisite learning |
Module Recommendations
This is prior learning (or a practical skill) that is strongly recommended before enrolment in this module. You may enrol in this module if you have not acquired the recommended learning but you will have considerable difficulty in passing (i.e. achieving the learning outcomes of) the module. While the prior learning is expressed as named DkIT module(s) it also allows for learning (in another module or modules) which is equivalent to the learning specified in the named module(s).
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No recommendations listed |
Module Indicative Content |
HPLC, Gas Chromatography, Mass Spectrometry
• HPLC - Principle. Instrumentation (columns, mobile phase, stationary Phase). Detectors (UV , Fixed Wavelength, Multi-wavelength , Diode Array, Electrical Conductivity, Fluorescence, Refractive Index, Tridet Multi Functional). Applications.
Separation Modes (Reverse Phase HPLC, Hydrophilic Interaction , Ion Exchange, Size Exclusion, Immobilised Metal Affinity, Chiral).
• Gas Chromatography - Principle. Instrumentation (injectors, columns, mobile Phase, stationary phase). Detectors (FID, Nitrogen-Phosphorus, Electron Capture, Katherometer). Sample preparation (derivatisation). Applications.
• Mass Spectrometry - Principle. Instrumentation - Ion source (Electrospray, MALDI). Analyser (TOF, Quadropole, Ion Trap, Fourier Transform, Electromagnetic, Hybrid Mass Spectrometers). Applications. Analyisis of Mass Spectra.
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Numerical evaluation of chromatographical systems.
Qualitative versus quantitative analysis. Measures of Chromatographic Performance:
Distribution/Partition Coefficient (KD); Retention – Time and Volume; Retention Factor/Capacity Factor; Selectivity Factor; Plate Theory & Column Efficiency; Resolution; Rate Theory (Van Deemter Equation). Calculation of concentration and purity by direct proportion and using internal and exteral standards.
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Capillary Electrophoresis, ELISA, Western blot, SDS-PAGE and 2D SDS-PAGE.
• Capillary Electrophoresis - Principle. Intrumentation (sample injection, capillary columns, detectors - UV, laser induced fluorescent detector). Applications. Separation modes (Capillary Zone Electrophoresis (CZE), Micellar Electrokinetic Chromatography (MEKC), Capillary Isoelectric Focusing (CEF), Capillary Isotachophoresis (CITP), Capillary Gel Electrophoresis (CGE), Affinity Electrophoresis, Capillary Electrochromatography (CEC)).
• Principles and applications of: ELISA, Western blotting, SDS-PAGE and 2D SDS-PAGE.
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Practical. HPLC, gas chromatography and capillary electrophoresis.
Students will use chromatographic and electrophoretic methods to check the purity of products. Students will analyze data from resulting chromatographs - resolution, retention times, column efficiency.
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Module Assessment
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Assessment Breakdown | % |
Course Work | 50.00% |
Final Examination | 50.00% |
Module Special Regulation |
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AssessmentsFull Time
Reassessment Requirement |
A repeat examination
Reassessment of this module will consist of a repeat examination. It is possible that there will also be a requirement to be reassessed in a coursework element.
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DKIT reserves the right to alter the nature and timings of assessment
Module Workload
Workload: Full Time |
Workload Type |
Contact Type |
Workload Description |
Frequency |
Average Weekly Learner Workload |
Hours |
Lecture |
Contact |
No Description |
Every Week |
3.00 |
3 |
Practical |
Contact |
No Description |
Every Week |
2.00 |
2 |
Directed Reading |
Non Contact |
No Description |
Every Week |
3.00 |
3 |
Independent Study |
Non Contact |
No Description |
Every Week |
3.00 |
3 |
Total Weekly Learner Workload |
11.00 |
Total Weekly Contact Hours |
5.00 |
This module has no Part Time workload. |
Module Resources
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Recommended Book Resources |
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Skoog, D., Holler, F. and Crouch, S.. (2007), Principles of instrumental analysis, Thomson.
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Rouessac, R. and Rouessac, A.. (2007), Chemical analysis: Modern instrumentation methods, 2nd. Wiley.
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Harris, D.. (2005), Quantitative chemical analysis, 6th. Cambridge University Press.
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Ardrey, B.. (2003), Liquid chromatography-mass spectrometry, Wiley.
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Weinberger, R.. (2001), Practical capillary electrophoresis, 2nd. Academic Press.
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Neue, U.. (1997), HPLC columns: Theory, technology and practice, Wiley.
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Kellner et al. Analytical Chemistry “A modern approach to analytical science”, 2nd Edition. Wiley, [ISBN: 3527305904].
| This module does not have any article/paper resources |
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Other Resources |
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[Website], Chemistry Hypermedia Project -
Chromatography,
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[Website], High Performance Liquid Chromatography
Mass Spectrometry (HPLC/MS) - Bristol
University,
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[Website], Introduction to mass-spectrometry,
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[Website], LCMS homepage,
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[Website], Sheffield Hallam University
Chromatography,
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[Link], Library Catalogue,
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